Calculation of the work function with a local basis set

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6 Calculation of the work function with a local basis set

Electronic structure codes usually allow to calculate the work function as a part of the theoretical description of surfaces and processes such as adsorption thereon. This requires a proper calculation of the electrostatic potential in all regions of space, which is apparently straightforward to achieve with plane wave basis sets, but more difficult with local basis sets. To overcome this, a re...

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ژورنال

عنوان ژورنال: Surface Science

سال: 2006

ISSN: 0039-6028

DOI: 10.1016/j.susc.2006.10.025